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Mark, I use a Canon 7D with a Canon 100mm IS macro lens handheld.Whilst good kit makes it easier to get good images it really is all about the light. Wherever possible I move the plants so that they are in good light whilst the background is in shadow. I shoot in aperture priority to control depth of field which can help the subject stand out. I shoot raw files and convert them in Breezebrowser using a high chroma setting that mimics Velvia film.As Peter suggests warm evening light makes a big difference -I have it available here on demand courtesy of the Grangemouth petrochemical complex.
Steve - thanks for that information; 'handheld' is the biggest surprise. Macros struggle for depth of field so do you compensate with a high ISO number?